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The first catalytic direct alkylation of allylic C-H bonds via Pd(II)-catalysis is described in the absence of base. Polysubstituted cyclic compounds can also be constructed by the intramolecular direct allylic alkylation.

Original publication

DOI

10.1021/ja803452p

Type

Journal article

Journal

J Am Chem Soc

Publication Date

01/10/2008

Volume

130

Pages

12901 - 12903